Empirical Viscosity–Concentration Relationship for Polymer Solutions
نویسندگان
چکیده
منابع مشابه
Soft Confinement for Polymer Solutions
As a model of soft confinement for polymers, we investigated equilibrium shapes of a flexible vesicle that contains a phase-separating polymer solution. To simulate such a system, we combined the phase field theory (PFT) for the vesicle and the self-consistent field theory (SCFT) for the polymer solution. We observed a transition from a symmetric prolate shape of the vesicle to an asymmetric pe...
متن کاملThermodynamics of Polymer Solutions
Most of the synthetic compounds are prepared and processed in the liquid state, i.e. in solution or in the molten state. Detailed knowledge on this state is therefore indispensable. In particular it is essential to know the limits of complete miscibility with a low molecular weight solvent as a function of temperature, pressure and composition. Furthermore it is often mandatory to be acquainted...
متن کاملTurbulence of polymer solutions.
We investigate high-Reynolds-number turbulence in dilute polymer solutions. We show the existence of a critical value of the Reynolds number, which separates two different regimes. In the first regime, below the transition, the influence of the polymer molecules on the flow is negligible, so they can be regarded as passively embedded in the flow. This case admits a detailed investigation of the...
متن کاملAccurate effective pair potentials for polymer solutions
Dilute or semidilute solutions of nonintersecting self-avoiding walk ~SAW! polymer chains are mapped onto a fluid of ‘‘soft’’ particles interacting via an effective pair potential between their centers of mass. This mapping is achieved by inverting the pair distribution function of the centers of mass of the original polymer chains, using integral equation techniques from the theory of simple f...
متن کاملQuantitative tube model for semiflexible polymer solutions.
We develop an analytical and quantitative theory of the tube model concept for entangled networks of semiflexible polymers. The absolute value of the tube diameter L perpendicular is derived as a function of the polymers' persistence length lp and mesh size xi of the network. To leading order, we find L perpendicular = 0.31xi 6/5 lp (-1/5) , which is consistent with known asymptotic scaling law...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Polymer Journal
سال: 1982
ISSN: 0032-3896,1349-0540
DOI: 10.1295/polymj.14.501